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MEMOIRS ON THE FUNDAMENTAL

The series of numbers representing electrochemical equivalents

must, like those expressing the ordinary equivalents of chemically acting bodies, remain subject to the continual correction of experiment and sound reasoning.

I give the following brief table of ions and their electrochemical equivalents, rather as a specimen of a first attempt than as anything that can supply the want, which must very quickly be felt, of a full and complete tabular account of this class of bodies. Looking forward to such a table as of extreme utility (if well constructed) in developing the intimate relation of ordinary chemical affinity to electrical actions, and identifying the two, not to the imagination merely, but to the conviction of the senses and a sound judgment, I may be allowed to express a hope, that the endeavor will always be to make it a table of real, and not hypothetical, electrochemical equivalents; for we shall else overrun the facts, and lose all sight and consciousness of the knowledge lying directly in our path.

The equivalent numbers do not profess to be exact, and are taken almost entirely from the chemical results of other philosophers in whom I could repose more confidence, as to these points, than in myself.

TABLE OF IONS
ANIONS
Oxygen8Phosphoric acid35.7
Chlorine35.5Carbonic acid22
Iodine126Boracic acid24
Bromine78.3Acetic acid51
Fluorine18.7Tartaric acid66
Cyanogen26Citric acid58
Sulphuric acid40Oxalic acid36
Selenic acid64Sulphur (?)16
Nitric acid54Selenium (?)
Chloric acid75.5Sulpho-cyanogen
CATIONS
Hydrogen1Calcium20.5
Potassium39.2Magnesium12.7
Sodium23.3Manganese27.7
Lithium10Zinc32.5
Barium68.7Tin57.9
Strontium43.8Lead103.5

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